Silicone rubber probably isn't a suitable choice. I've tried to make castings that are stiff (resistant to compression was what I was after), and it wasn't easy. I first tried adding powdered chalk/marble and then tried fumed silica. The problem with both was that the liquid became almost too thick to pour. With the chalk, I got a reasonable result for what I wanted, but pouring didn't work well - most of it poured, but it didn't settle or level well. With the fumed silica, it was marginal for pouring, but the result was still too soft. All of my test bits were still pretty flexible. Another issue with thickening the stuff up with an additive is that it becomes harder for air bubbles to leave while it's curing. (In professional setups, they use a vacuum chamber to pull the bubbles out.)
For the bellows, the difficulties are compounded because the bits need to be pretty thin to stop the bellows being too bulky for short focal lengths, or when the camera is folded. Given that my test pieces were 5mm thick, and noticably flexible, I suspect a thickness suitable for bellows (1mm max?) will add very little in terms of structural rigidity.
Silicone is also quite heavy with a specific gravity around 1.2 to 1.3 (and some go outside that range), so sag might also be an issue depending out how much flex there is in the light tight material.
That said, Tiranti do a wide range of silicone rubbers, should you be interested...
http://www.tiranti.co.uk/EdgeImpactShop/subcategory.php?Subcategory=51&Content=Silicone+Rubber
I've used them once so far, and found the service very good.