When you're shooting shallow depth of field/longish exposure portraits like this, rear curtain is usually a bad idea as any movement from you or subject during exposure will cause the captured shot to be out of focus
This would make me think the flash is definitely not firing as at iso 1250 and I'm guessing around f2 a flash that close at over half power I'd expect the subject to be seriously overexposed?
You should really be able to drop the iso and shutter a bit if you get the issues sorted with the flash. Here's a couple of out-takes from last year and year before, not saying they're the best images ever, but pretty much sooc for an idea. Flash powers are a bit guessy as from memory but both lit with single yn-560 with a rosco cto gel in a 60inch umbrella. Still need to shoot a christmas photo for this year
d700, 50mm @ 1.8, iso 200, shutter 1/60, flash around 1/8
d7000, 50mm @1.8, iso 800, shutter 1/20, flash around 1/32, background is a bit blown on this one and guessing my white balance was auto as YELLOW!
I'm not familiar with the canon system but if you're struggling to get the commander mode working and using manual on flash you could try setting it just to optical slave and set your on camera flash to min power with a wee bounce card to keep it off the subject to trigger it.