Remember also the centre point is generally/always(?) a "cross" type AF point and outer ones not always, certainly not all of them anyway(cant recall if its horizontal or vertical sensitive , but its one and not both). So if you use an outer point and choose the wrong format it wont necessarily work as well as it should or the centre point.
Just a centre point makes it very awkward to compose a shot using an off centre point of interest (or what you want to focus on). It can be done though. Use single af mode (i.e. one that doesnt change when you move the camera around, so no servo/ai servo), lock onto your point of interest, focus (using Af) then re-compose but be careful not to do it in arc motion or you'll be off focus again.
Matt