Yes I'd agree with the above, its likely that you will need to combine your images in PP, particularly if you want a nice starry dark sky and the building lit up.
I would probably take a test exposure and look to getting the sky right first, so that would be at a wide aperture, high ISO and shutter speed of not more than 25 seconds ish (unless you want star trails). Focus on a star or the moon, manual focus, any vibration reduction off.
Once you have done that now frame the shot with the building in the place where you want it. Take several shots so you get a sky your happy with.
Then without moving the camera I'd light paint the building. Manual focus, put your torch by the building and use it to aid your focus. Here you will want a lower ISO 100-200 an aperture around f5.6 / f8 and shutter you will have to use the bulb setting and try a minute exposure as a starter for 10. Also long exposure noise reduction off (unless you want to take a tent and a sleeping bag!) Then you can paint round the building with your torch try and use diffused light not a pinpoint beam, diffuse your torch with greaseproof paper if you like.
I'm no expert at light painting but have done a bit in the past, BTW its a good idea to not use a LED torch as they tend to be a bit blue and use something like Incandescent for white balance, wear dark or black clothes use a red torch for setting up your camera it preserves your night vision. Take plenty of spare batteries. Look up light painting there is bound to be bags of info on line about it.
I think light painting will give you a much more subtle light on the building rather than a harsh flash, and the other advantage is you can determine where the light is going to be on the building rather than flooding the foreground and other objects with light.
Just my 2d Roy, it will take a bit of practise but worth a try.... cant wait to see the result on TP