CS5 runs in 32bit so you wouldn't need anything.
Why would you want to change, just for speed ?
Maybe that refers to the CPU?
Anyway it should work fine in 32bit but a bit(!) faster in 64bit.
If you want 64bit, you need to upgrade your operating system.
if you can afford it upgrade to win 7, much better os and lighter on resources
64bit requires more memory than 32bit systems as well
adobe dont mention needing 64bit for photoshop cs5..
http://www.adobe.com/products/photoshop/photoshop/systemreqs/
sure you downloaded the correct trial?
64bit requires more memory than 32bit systems as well
A 64-bit O/S can address more memory than 32-bit. It doesn't in itself need more.

A 64-bit O/S can address more memory than 32-bit. It doesn't in itself need more.
Well, since the memory addresses are twice as large (64-bit pointers instead of 32-bit) applications and the OS will need roughly twice as much memory to store and retrieve the locations of data in use, even if the address itself is capable of being described fully in a 32-bit word.
This won't mean that 64-bit applications will use twice as much memory as in a 32-bit environment (not all data being handled consists of pointers and with large data sets it may be that there are some efficiencies compared with 32-bit workarounds) but it's likely that they will require more memory to operate at a base level.