Glacial acetic acid gets its name from its high freezing point (52 degrees F)- so it should be stored at a reasonable temperature. It's the working part of a conventional stop bath, highly diluted with water. It has the characteristic smell of vinegar, unlike the citric acid used in odourless stop baths. I prefer acetic acid, because pickled onions don't go mouldy, and lemons do - indicating that acetic acid lasts longer withour mould. The glacial form is highly corrosive (so immediate wash if it gets on you) and also highly inflammable.
Sodium metabisulphite (Thanks - I couldn't make out the label) is generally used as an additive to make fixer acidic. It can also be used as a preservative for pyrogallol.
Hydrogen peroxide is used as a hypo eliminator; but an interesting side effect is that an acidic solution (or vapours from same) can fog sensitive materials.