Best Black & White Enhancing software.

Lightroom
 
Silver Efex
 
Lightroom and a good working knowledge of colour theory and how colours translate into tones... then do it yourself instead of relying on plug ins... it's actually faster when you know what you're doing and making adjustments yourself as even with SFX you have to sit there clicking through a massive list of presets until you find one that fits the bill.

Unless you mean black and white effects such as detail extraction and micro contrast adjustments.. then probably SilverFX... but if you just mean making a black and white image with a good tonal range... Lightroom.
 
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