Digital generally has a litle more dynamic range than slide film, but colour neg has tons of it, potentially, because it will handle massive over exposure.
Colour neg has DIR colour-couplers (Dye Inhibiter Release or summat like that) which stops development taking place and the highlights going darker. So when you increase the exposure the shadows get more and more detail in them, but the highlights stay more or less where they are. That's the gist of it I think.
It was this film technology that made disposal cameras possible, with their fixed exposure setting. They're adjusted for correct exposure in fairly dull light, in the knowledge that they'll still be okay in bright sun.
It's not an ideal way of doing things, but it works surprisingly well in holding back skies and areas where tonal subtlety and fine detail are less important.
It was common to use an aspect of this development inhibitor technique when processing black & white negs and prints - Andsel Adams used it as part of the Zone System. Basically, don't agitate the developer, as you would normally. Then the chemicals get exhausted around the dark highlight areas, but they keep going in the lighter shadow areas. It's a kind of HDR technique.