I don't think it is so much the way the sky looks as the difference that is apparent in the sky comparred to the Castle. Because you have altered the levels in the sky it has created sharp lines around the windows which is usually a sign of a badly imported background. By increasing the contrast of the building, and applying some sharpening to balance the detail in the brickwork with the sharp edges around the windows it would balance the photo much more. If done correctly it could work and make what is essentially a good picture into a very good picture.
You need to work on the contrast and shapness of the building to balance the picture
In addition to above, have you tried the sky looking more greay, as this would tone better with the stone work. In addition if sky is anothey layer, then decrease opacity of sky level to allow original colours of sky to bleed through a little. On your original shot on another thread I had opacity at around 85% for that reason.
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