Congrats on getting a KF, well done.
The images do look a little soft, it seems to be a missed focus thing, mixed with motion blur maybe. Cropping will bring out the softness even more. Was there anything in front of the lens( glass/perspex)? I'm assuming there wasn't but it's worth the ask. You've had tons of light by the looks of it too, so I'm thinking shutter speed versus aperture shouldn't be a problem as such here, which will help of course. Strong, contrasty, what looks like direct sun light won't help though.
It may be heat haze or something atmospherical?
I wonder is your lens back or front focusing?
I'm suprised you found the Sigma slow to focus, I have that lens for my Canon bodies and have found it almost as snappy as my L glass. In fact, I would say that the Sigma was just as fast and also, as sharp as the 100-400L Mk1 that I once owned, to the point that I almost sold the Canon. I have a thing about letting good glass go though and I hung on to it until recently, when I got the Mk2. I would say the Mk2 is quicker than the Sigma, as well as sharper (it's ridicolously so actually) but the Sigma is still no slouch and a lens I'll be keeping. I do feel the Canon (Mk2) also resolves the sensor better than the Sigma, it seems to get every single pixel out of my R7 and 5Div.
f6.3 isn't ideal, although the 600mm can be very handy. I've managed to get decent KF images with my Sigma, infact, until I bought the 100-400Mk2, it was my go to lens and has been a real workhorse. The shutter speeds would drop at the end of the day for sure, but with a little patience and picking my moment, I could still get them sharp, even at 1/125 sec. Forget anything moving at that shutter speed though.
I've never used a 600mmf4 and I can imagine, you'd know where the money went if you used one but I have often thought to myself is f4 £0000s better than 6.3 (or 5,6 on the 100-400)? I'm not knocking the big lenses, they are works of art and I appreciate the expensive lenses come into their own in lower light levels, where the Sigma would/does struggle.
The Sigma will always be a compromise but it does a great job in my opinion.