Personally, any shots I take of sunsets (or sunrises these days!) are shot bareback - after all, the sun and the light around it are the main subject so (for me) there's no need for any grads and (as already said above) there's little point in using a pol when shooting straight into the sun - any reflections of the sunset are likely to add to the shot rather than detract. I usually dial in a stop or so of underexposure to boost the colours but I usually take an early shot then decide whether the later ones need it or not - it's a matter of personal taste.