This was the info which solved it for me.
https://forum.synology.com/enu/viewtopic.php?t=97097
"Configuring a static IP on the NAS requires a little bit of homework on your part. First step is to determine what device is giving out IP Addresses to the network, ie, your DHCP server. The easiest way to determine this is by using your Windows7 machine.
Start > (Instant Search) type in cmd and click on "Command Prompt" in the search result above.
After you click on it, you'll see a black window with a cursor.
type in ipconfig /all and press enter. The command will spit out a whole bunch of information for you. If you are connected with a network cable you want to find the section with "Ethernet Adapter Local Area Connection" If you are wireless, find the section called "Wireless LAN adapter..."
You are looking for a few key pieces of information to record for your static IP assignment.
1. IPv4 Address
2. Subnet Mask
3. Default Gateway
4. DHCP Server
5. DNS Server(s)
This information is crucial in helping to assign the IP of your NAS.
Once you have written down this information, the next step is to find out the DHCP scope of your network. Your DHCP server is most likely your main router that everything connects to in your home to access the internet. If you have access to the device to make configuration changes, then log in and look through the configuration for the DHCP Scope. The scope is the starting and ending IP address range that the device uses to hand out IP addresses for use. It will most likely not be labeled a scope, so pay attention to anything that may look like an address range that is being handed out for use on the network. If you find this, write down the starting and end IP address for your scope.
If you don't have any way of determining your DHCP scope, your best bet is to assign an IP address at the opposite end of the address range.... keep reading.
Now comes the most fun part of the process, taking everything you have and combining it to determine what IP address you can use for your static IP.
Let's say for instance your configuration looks like this:
IPV4 Address: 192.168.1.2
Subnet: 255.255.255.0
Default Gateway: 192.168.1.1
DHCP Server: 192.168.1.1
DNS Server: 192.168.1.1
DHCP Scope: 192.168.1.2 - 192.168.1.100
The subnet mask is used to determine what constitutes as the "Local" network. If you match up your IPv4 Address and subnet above each other like so....
192.168.1.2
255.255.255.0
Each octet of the IPv4 address that corresponds to a 255 octet of your subnet, must match the IPv4 address to your NAS... ie... 192.168.1
If the octet of the subnet mask is 0 that means you can use ANY UNSUED number in that last octet between 1 and 254.
The key is to make sure what address you assign is OUTSIDE your DHCP scope, which is why we looked it up.
So if your scope is 192.168.1.2 - 192.168.1.100 then you can assign your NAS any IPv4 address from 192.168.1.101 - 192.168.1.254.
If you were unable to find your scope and your router is .1, I would assign .254 to the NAS after determining there are no active devices on that IP.
To determine an IP unused, use the command prompt window and type in ping 192.168.1.254 (the address you want to verify) and press enter. You should see a timeout. Let it timeout all four times then type in arp -a and press enter. If you do not see a result for the address you ping'ed then there is no active device on that IP and you can use it. Remember... this is not fool proof if you don't know the DHCP scope, it is just ensuring it is open at the moment but there is a potential for a device on that IP.
The rest of the settings in your NAS should match your W7 machine... subnet mask, default gateway and DNS servers."