The problem there was probably not one of exposure, but of brightness range, or dynamic range. Basically, the sky is so much brighter than the foregorund that the sensor can't handle it and adjusting the exposure won't change that. If you set it to make the sky darker, the foreground will go black.
The easiest way to sort that out is with a polarising filter, and they work really well on blue sky, but they do almost nothing on a bright but overcast day. Then you could try a grad ND filter (graduated, neutral density ie grey) which just darkens the top of the picture. Third option is to try HDR technique, High Dynamic Range, which invloves shooting several frames at different exposure levels and merging them in post processing.
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