For what you want to do it sounds like a tripod would be a better idea, if your trying to camture the " look" of the street at night flash will ruin the effect (to a certain extent) you just want the ambiant lighting, flash is better for lighting your subject maybe in the foreground, but as said you'll have to balance the colours (or use black and white)
Flash also has a place in daylight, fill in flash, thats use to lighten the shadows maybe on your sbjects face in sunshine, wedding togs use it a lot of time.