The two transitions are in fact identical - the only difference between A and B being, in A, the transition is in the blue spectrum (R150,G200,B150 -> R150, G200, B100) and in B it is in the red spectrum (R150,G200,B150 -> R100, G200, B150).
The theory goes that as far as your colour vision is concerned, your blue sensitive cones only exist around the periphery of your vision, the detailed area being made up predominately of red and green sensitive cones, so where colour boundaries are caused by a change in the blue spectrum only, you generally do not perceive the transition as 'sharp'.
If the theory is correct, you should see B as sharper.