Forget what I said about lightroom, I have a better method. In PS use the colour balance with a mask to kepp the redness of the dress, it took about 1 minute.
The lighting is possibly a little flat also a hair light from behind would make the face stand out more. Bring the model away from the backdrop and you will then get rid of the shadow. I think you cold possibly get a bit more contrast without blowing out the highlights.
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